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Whereas the reaction of most Cys-thiols and H 2 O 2 at physiological pH is slow (137, 138), a Cys-perthiolate anion is likely to be dramatically more reactive with H 2 O 2 , forming Cys-persulfenylate (Cys-SSO − ) and possibly Cys-persulfinylate (-SSO 2 − ) and -persulfonylate (-SSO 3 − ) anions upon subsequent reactions with additional equivalents of H 2 O 2 (Fig